|Publication Type||Journal Article|
|Year of Publication||2008|
|Authors||Rahaim, RJ, Shaw, JT|
|Journal||J Org Chem|
|Date Published||2008 Apr 04|
|Keywords||Alkynes, Catalysis, Molecular Structure, Organometallic Compounds, Organosilicon Compounds, Stereoisomerism, Zinc|
A rapid and high-yielding silylation of terminal alkynes employing TMSOTf and catalytic quantities of Zn(OTf)2 has been developed. The reaction works well for a variety of substrates including reactive esters. Fifteen examples with yields of >90% are reported.
|Alternate Journal||J. Org. Chem.|