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The Journal of organic chemistry DOI:10.1021/jo1022926

Large-scale synthesis of all stereoisomers of a 2,3-unsaturated C-glycoside scaffold.

Publication TypeJournal Article
Year of Publication2011
AuthorsGerard, B, Marié, JC, Pandya, BA, Lee MD, 4th, Liu, H, Marcaurelle, LA
JournalThe Journal of organic chemistry
Volume76
Issue6
Pages1898-901
Date Published2011/03/18
ISSN0022-3263
Abstract

All stereoisomers of a highly functionalized 2,3-unsaturated C-glycoside can be accessed in 10-100 g quantities from readily available starting materials and reagents in 3-7 steps. These chiral scaffolds contain three stereogenic centers along with orthogonally protected functional groups for downstream reactivity.

URLhttp://dx.doi.org/10.1021/jo1022926
DOI10.1021/jo1022926
Pubmed

http://www.ncbi.nlm.nih.gov/pubmed/21341742?dopt=Abstract