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Zinc-catalyzed silylation of terminal alkynes.
|Publication Type||Journal Article|
|Authors||Rahaim RJ, Jr, and Shaw JT|
|Abstract||A rapid and high-yielding silylation of terminal alkynes employing TMSOTf and catalytic quantities of Zn(OTf)2 has been developed. The reaction works well for a variety of substrates including reactive esters. Fifteen examples with yields of >90% are reported.|
|Year of Publication||2008|
|Journal||The Journal of organic chemistry|
|Date Published (YYYY/MM/DD)||2008/04/04|